The fuel bouncing around would speed evaporation by increasing surface area. In other words, it would reach vapor pressure more quickly as the temperature goes up, or after something like a fuel fill up. When you stop for gas and woosh the cap, you release the vapor pressure. But it will re-attain that pressure when you put the cap back on.
About the backpack blower... It's my understanding that the check valve in the cap allows air INTO the tank, but doesn't let anything out. My understanding is that entire system is supposed to operate under a vacuum as fuel is removed from the tank. If one would ask the question "so why doesn't the tank pressure go up on that" I don't have a good answer. I don't know why your blower ends up in a puddle of fuel when you shut it off.
And maybe even more important... I don't know why mine doesn't.
Maybe because you're taking fuel out so fast? Maybe because the float chamber is atmospherically controlled? Don't know, and now it bugs me. Thanks a lot.