I can't help but wonder whether this situation would respond better to big heat and big torque. As in, welding a nut onto the top of the stud and then putting a wrench on it. IIRC, @grannyknottalked about this in another thread a couple of years ago when the topic was extracting a snapped-off manifold stud out of the cylinder head. Something about the merits of using an oxyacetylene torch rather than a MIG?
The difference here is that we have a large-diameter stud (bolt shank) that's seized inside a cast-iron engine block (vs. a small-diameter stud seized inside an aluminum head). Whereas it's the galvanic action of dissimilar materials that typically creates problems with steel fasteners getting stuck in alloy castings, for a head bolt it's steel-in-iron so I would think that the causes for the locked threads would be simple air (oxygen)-generated corrosion (unless the block has a micro-crack and coolant (water) has leached into the stud threads -- but let's not talk about that).
In my (limited) experience of removing cylinder heads from high-mileage L24's, the head bolts take a lot of torque to break free and some of them really pop when they give way. Looking at the threads after the bolts came out, they appeared 'sooty' but not really crusty-rusty. I think that part of the problem with these head bolts getting stuck in the block is that they were installed at the factory without any lubrication so as to get accurate torque readings during tightening.
Having said all that, I will repeat another story that I wrote about previously. In my area of the world (on the fringes of a 7-million pop. Canadian city), I discovered a contractor who provides the new-car retail industry with specialist services for extracting frozen fasteners from customer cars. That's all he does. He told me that there a certain model years for certain higher-end car brands where a key fastener (e.g. suspension mount) is chronically frozen, hard to get at, and often snaps off during attempted removal. That's where he makes his money. I hired him to get the snapped-off studs out of my Z's cylinder head (still mounted on the engine, in the car) and it was one of the best $120 I ever spent. He came to my house, rolled a tool caddy out of his truck, sized things up, and had the job done (without using any heat) in 10 minutes tops. Cheating? Maybe. Depends on your threshold for potentially-painful outcomes. You might consider looking for a comparable specialist in your area. The service managers at your local Benz, BMW, Audi and Volvo dealers might be able to help you find one.